Electrocatalysts are a specific form of catalysts that function at electrode surfaces or may be the electrode surface itself. An electrocatalyst can be heterogeneous such as a platinum surface or nanoparticles, or homogeneous like a coordination complex or enzyme. The electrocatalyst assists in transferring electrons between the electrode and reactants, and facilitates an intermediate chemical transformation described by an overall half reaction. Electrocatalysis may be defined as the relative ability of different substances, when used as electrode surfaces under the same conditions, to accelerate a given electrochemical process.
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