The mechanism of bacterial synthesis of polymers and copolymers of hydroxyalkanoic acids is described. The structural and physicochemical properties of polymers obtained by biosynthesis are identical to those of the polymers obtained by polymerisation of lactones. Polymers and copolymers of hydroxyalkanoic acids are readily crystallisable flexible-chain polymers, capable of forming films and fibres when the degree of polymerisation is higher than 500–600. These compounds are biodegradable.
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